W, Mo, and W–Mo alloy films are prepared on 316L stainless steel by means of ion beam assisted deposition (IBAD). Tribological behaviors of the treated surfaces are investigated under lubrication with molybdenum dialkyldithiocarbamate (MoDTC) on a MS-T3000 friction and wear tester. The micromorphologies and chemical characteristics of the tribofilms generated on the worn surfaces are analyzed by scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS), respectively. The results showed that the obvious synergistic effects of better friction reduction and wear resistance between W–Mo film and MoDTC are attributed to the hard surface and the high decomposition rate of additives on the worn W–Mo surface.
Issue Section:
Coatings and Solid Lubricants
References
1.
Donnet
, C.
, and Erdemir
, A.
, 2004
, “Historical Developments and New Trends in Tribological and Solid Lubricant Coatings
,” Surf. Coat. Technol.
, 180–181
, pp. 76
–84
.2.
Holmberg
, K.
, and Mathews
, A.
, 1994
, “Coatings Tribology: A Concept, Critical Aspects and Future Directions
,” Thin Solid Films
, 253
(1–2
), pp. 173
–178
.3.
Pradip
, K. S.
, 1998
, “Thermodynamics and Tribology in Aluminum Extrusion
,” Wear
, 218
(2
), pp. 179
–190
.4.
Tang
, J. G.
, Liu
, D. X.
, Tang
, C. B.
, Zhang
, X.-H.
, Xiong
, H.
, and Tang
, B.
, 2012
, “Tribology Behavior of Double-Glow Discharge Mo Layers on Titanium Alloy in Aviation Kerosene Environment
,” Trans. Nonferrous Met. Soc. China
, 22
(8
), pp. 1967
–1974
.5.
Vanhulsel
, A.
, Velasco
, F.
, Jacobs
, R.
, Eersels
, L.
, Havermans
, D.
, Roberts
, E. W.
, Sherrington
, I.
, Anderson
, M. J.
, and Gaillard
, L.
, 2007
, “DLC Solid Lubricant Coatings on Ball Bearings for Space Applications
,” Tribol. Int.
, 40
(7
), pp. 1186
–1194
.6.
Carr
, G. E.
, and Conde
, R. H.
, 2008
, “Tribology of Hard Coating Alloys Deposited by Thermal Methods: Applications to Industrial Components
,” Surf. Coat. Technol.
, 203
(5–7
), pp. 685
–690
.7.
Wang
, H. D.
, Xu
, B. S.
, Liu
, J. J.
, and Zhuang
, D.-M.
, 2005
, “Microstructures and Tribological Properties on the Composite MoS2 Films Prepared by a Novel Two-Step Method
,” Mater. Chem. Phys.
, 91
(2–3
), pp. 494
–499
.8.
Wang
, H. D.
, Xu
, B. S.
, Liu
, J. J.
, and Zhuang
, D.-M.
, 2007
, “Molybdenum Disulfide Coating Deposited by Hybrid Treatment and Its Friction-Reduction Performance
,” Surf. Coat. Technol.
, 201
(15
), pp. 6719
–6722
.9.
Zhu
, L. N.
, Wang
, C. B.
, Wang
, H. D.
, Xu
, B. S.
, Liu
, J. J.
, and Li
, G. L.
, 2011
, “Structure and Tribological Behaviors of Synthetic MoS2 Film Prepared by a Novel Compound Method
,” Adv. Mater. Res.
, 217–218
, pp. 1102
–1107
.10.
Ning
, Y. P.
, Wang
, W. W.
, Sun
, Y.
, Wu
, Y.
, Liu
, Y.
, Man
, H.
, Malik
, M. I.
, Wang
, C.
, Zhao
, S.
, Tomasella
, E.
, and Bousquet
, A.
, 2016
, “Effects of Substrates, Film Thickness and Temperature on Thermal Emittance of Mo/Substrate Deposited by Magnetron Sputtering
,” Vacuum
, 128
, pp. 73
–79
.11.
Anna
, M. H.
, Gregor
, M.
, Alexander
, F.
, Winkler
, J.
, and Mitterer
, C.
, 2016
, “Improvement of Oxidation and Corrosion Resistance of Mo Thin Films by Alloying With Ta
,” Thin Solid Films
, 599
, pp. 1
–6
.12.
Santos
, P. F.
, Niinomi
, M.
, Liu
, H. H.
, Cho
, K.
, Nakai
, M.
, Trenggono
, A.
, Champagne
, S.
, Hermawan
, H.
, and Narushima
, T.
, 2016
, “Improvement of Microstructure, Mechanical and Corrosion Properties of Biomedical Ti–Mn Alloys by Mo Addition
,” Mater. Des.
, 110
, pp. 414
–424
.13.
Greenwood
, O. D.
, Moulzolf
, S. C.
, and Blau
, P. J.
, 1999
, “The Influence of Microstructure on Tribological Properties of WO3 Thin Films
,” Wear
, 232
(1
), pp. 84
–90
.14.
Kim
, Y.
, and Choi
, H. Y.
, 2017
, “Characterization of Ti/W, Ti/Cr, and Ti/Pt Thin Films—Part I: Surface Morphologies and Nano-Mechanical Properties
,” Sens. Actuators A
, 254
, pp. 9
–19
.15.
Yu
, J.
, Han
, W.
, Chen
, Z.
, and Zhu
, K.
, 2016
, “Comparison of Blistering of W Bulk and Film Deposited by Magnetron Sputtering Under Helium Irradiation
,” Nucl. Mater. Energy
(in press).16.
Wei
, J. J.
, Zhang
, X. S.
, and Xue
, Q. J.
, 2008
, “The Tribological Properties of Ceramic Coatings Modified by Molybdenum Films Under Oil-Lubricated Conditions
,” Thin Solid Films
, 266
(1
), pp. 48
–51
.17.
Haseeb
, A. S. M. A.
, Albers
, U.
, and Bade
, K.
, 2008
, “Friction and Wear Characteristics of Electrodeposited Nanocrystalline Nickel–Tungsten Alloy Films
,” Wear
, 264
(1–2
), pp. 106
–112
.18.
Vipin
, S.
, Ujjwal
, P.
, and Manoj Kumar
, B. V.
, 2015
, “Surface Composites by Friction Stir Processing: A Review
,” J. Mater. Process. Technol.
, 224
, pp. 117
–134
.19.
Sgroi
, M. F.
, Asti
, M.
, Gili
, F.
, Deorsola
, F. A.
, Bensaid
, S.
, Fino
, D.
, Kraft
, G.
, Garcia
, I.
, and Dassenoy
, F.
, 2017
, “Engine Bench and Road Testing of an Engine Oil Containing MoS2 Particles as Nano-Additive for Friction Reduction
,” Tribol. Int.
, 105
, pp. 317
–325
.20.
Griffiths
, C. A.
, Rees
, A.
, Kerton
, R. M.
, and Fonseca
, O. V.
, 2016
, “Temperature Effects on DLC Coated Micro Moulds
,” Surf. Coat. Technol.
, 307
(Pt. A
), pp. 28
–37
.21.
Spikes
, H.
, 2004
, “The History and Mechanisms of ZDDP
,” Tribol. Lett.
, 17
(3
), pp. 469
–489
.22.
Morina
, A.
, Neville
, A.
, and Priest
, M.
, 2006
, “ZDDP and MoDTC Interactions and Their Effect on Tribological Performance—Tribofilm Characteristics and Its Evolution
,” Tribol. Lett.
, 24
(3
), pp. 243
–256
.23.
Li
, G. Y.
, Xu
, J. H.
, Zhang
, L. Q.
, Wu
, L.
, and Gu
, M.
, 2001
, “Growth, Microstructure, and Microhardness of W/Mo Nanostructured Multilayers
,” J. Vac. Sci. Technol. B
, 19
(1
), pp. 94
–97
.24.
Li
, G.
, Han
, Z.
, Tian
, J.
, Zhang
, L.
, and Gu
, M.
, 2003
, “A Study on the Interface Microstructure and Superhardness Effect of W/Mo Multilayer
,” Raremetal Mater. Eng.
, 42
(6
), pp. 2
–5
.25.
Wen
, S. Z.
, and Huang
, P.
, 2002
, Principles of Tribology
, 2nd ed., Tsinghua University Press
, Tsinghua, China
, Chap. 5.26.
Zhang
, K. D.
, Deng
, J.
, Meng
, R.
, Lei
, S.
, and Yu
, X.
, 2016
, “Influence of Laser Substrate Pretreatment on Anti-Adhesive Wear Properties of WC/Co-Based TiAlN Coatings Against AISI 316 Stainless Steel
,” Int. J. Refract. Met. Hard Mater.
, 57
, pp. 101
–114
.27.
Muthuraja
, A.
, and Senthilvelan
, S.
, 2015
, “Adhesive Wear Performance of Tungsten Carbide Based Solid Lubricant Material
,” Int. J. Refract. Met. Hard Mater.
, 52
, pp. 235
–244
.28.
Michael
, T.
, Nina
, S.
, and Rostislav
, D.
, 2016
, “Advanced Characterization Methods for Wear Resistant Hard Coatings: A Review on Recent Progress
,” Surf. Coat. Technol.
, 285
, pp. 31
–46
.29.
An
, V.
, Bozheyev
, F.
, Richecoeur
, F.
, and Irtegov
, Y.
, 2011
, “Synthesis and Characterization of Nanolamellar Tungsten and Molybdenum Disulfides
,” Mater. Lett.
, 65
(15–16
), pp. 2381
–2383
.30.
Zhu
, L. N.
, Wang
, C. B.
, Wang
, H. D.
, Xu
, B.-S.
, Zhuang
, D.-M.
, Liu
, J.-J.
, and Li
, G.-L.
, 2012
, “Microstructure and Tribological Properties of WS2/MoS2 Multilayer Films
,” Appl. Surf. Sci.
, 258
(6
), pp. 1944
–1948
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